Rh(I)-catalyzed intramolecular hetero-[4+2] cycloaddition of ω-alkynyl-vinyl oximes |
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| Authors: | Akio Saito |
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| Affiliation: | Laboratory of Organic Reaction Chemistry, Showa Pharmaceutical University, 3-3165 Higashi-tamagawagakuen, Machida, Tokyo 194-8543, Japan |
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| Abstract: | Cationic rhodium(I) catalyst derived from [RhCl(cod)]2 and AgSbF6 in hexafluoroisopropanol (HFIP) efficiently catalyzed the formation of bicyclic pyridine derivatives by intramolecular hetero-[4+2] cycloadditions of ω-alkynyl-vinyl oximes. |
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| Keywords: | Rhodium Hetero-[4+2] cycloaddition Vinyl oxime |
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