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Non-linear reciprocity in extended thermodynamics from the Robertson formalism
Authors:RE Nettleton
Institution:(1) Department of Physics, University of the Witwatersrand, Johannesburg 2050, South Africa, ZA
Abstract:Robertson has found a projection operator which, applied to the Liouville equation, yields an exact equation for , the information-theoretic phase-space distribution. If the Robertson equation is multiplied by a set 0pt]{} of functions representing physical fluxes, odd under momentum reversal and even under configuration inversion, a set of evolution equations is obtained for time-dependent ensemble averages which are variables of extended thermodynamics. In earlier work, a perturbation calculation was developed, assuming just one variable , for an operator 0pt] occurring in the Robertson equation. This calculation is extended here to the case where there are variables. The coefficients in the evolution equations depend on {} and explicitly on time t at short times. It is shown here that these coefficients exhibit Onsager symmetry at long times, after the transient explicit t-dependence has disappeared, to . Received 13 September 1999 and Received in final form 4 April 2000
Keywords:PACS  05  70  Ln Nonequilibrium and irreversible thermodynamics - 05  20  Jj Statistical mechanics of classical fluids - 05  60  Cd          Classical transport
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