Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol,and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis |
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Authors: | Ramachandran P Veeraraghavan Chandra J Subash Ram Reddy M Venkat |
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Institution: | Herbert C. Brown Center for Borane Research, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-1393, USA. chandran@purdue.edu |
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Abstract: | A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways. |
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