Catalytic, asymmetric synthesis of the C(1)(')-C(10)(') segment of pamamycin 621A |
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| Authors: | Calter M A Bi F C |
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| Affiliation: | Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061-0212, USA. calter@chem.rochester.edu |
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| Abstract: | [reaction--see text] This paper describes a catalytic, asymmetric approach to the C(1)(')-C(10)(') segment of pamamycin 621A. We synthesize this segment in a convergent manner, with each of the coupling partners ultimately deriving from enantiomerically enriched methylketene dimer. |
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