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Catalytic, asymmetric synthesis of the C(1)(')-C(10)(') segment of pamamycin 621A
Authors:Calter M A  Bi F C
Institution:Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061-0212, USA. calter@chem.rochester.edu
Abstract:reaction--see text] This paper describes a catalytic, asymmetric approach to the C(1)(')-C(10)(') segment of pamamycin 621A. We synthesize this segment in a convergent manner, with each of the coupling partners ultimately deriving from enantiomerically enriched methylketene dimer.
Keywords:
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