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Analyse multielementaire instrumentale des phosphates marocains par photoactivation nucleaire
Authors:V Galatanu  CH Engelmann
Institution:1. Département de Chimie Appliquée et d'Etudes Analytiques, Service d'Etudes Analytiques, Section d'Etudes et d'Analyse Isotopique et Nucléaire, CEN-Saclay, B.P. no. 2, 91190, Gif sur Yvette, (France)
Abstract:Photonuclear activation and high resolution gamma-ray spectrometry have been used to determine non-destructively the concentrations of 25 trace elements in Maroccan phosphate rock. The activation was simultaneously performed for phosphate samples and multielement standards in the bremsstrahlung beam of a linear electron accelerator at 18 and 30 MeV maximum energies. Gamma-ray spectra were recorded with a 79 cm3 Ge(Li) detector and a programmable analyzer IN 96. A detailed study of interferences was carried out. Limits of detection between 0.5 and 125 μg·g?1 were obtained.
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