| 单组分桥联茂基二异丙胺基钕配合物催化甲基丙烯酸甲酯聚合 |
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| 引用本文： | 滕洪祥,应来强,韩双成,唐文红,巴晓薇,赵钰滢,李刚,唐涛,金鹰泰. 单组分桥联茂基二异丙胺基钕配合物催化甲基丙烯酸甲酯聚合[J]. 应用化学, 2001, 18(3): 246-0 |
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| 作者姓名： | 滕洪祥 应来强 韩双成 唐文红 巴晓薇 赵钰滢 李刚 唐涛 金鹰泰 |
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| 作者单位： | 1. 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室，中国科学院、中国石油化工总公司高分子联合开放实验室 长春130022
2. 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室，中国科学院、中国石油化工总公司高分子联合开放实验室 长春 130022 |
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| 摘 要： | 催化聚合;茂稀土胺化物;单组分桥联茂基二异丙胺基钕配合物催化甲基丙烯酸甲酯聚合
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| 关 键 词： | 催化聚合 茂稀土胺化物 单组分桥联茂基二异丙胺基钕配合物催化甲基丙烯酸甲酯聚合 |
| 文章编号： | 1000-0518(2001)03-0246-02 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2000-05-14 |
Polymerization of MethylMethacrylate(MMA) Catalyzed by Bridged Lanthanocene Amide as Single-Component Catalyst |
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| TENG Hong Xiang,YING Lai Qiang,HAN Shuang Cheng,TANG Wen Hong,BA Xiao Wei,ZHAO Yu Ying,LI Gang,TANG Tao,JIN Ying Tai. Polymerization of MethylMethacrylate(MMA) Catalyzed by Bridged Lanthanocene Amide as Single-Component Catalyst[J]. Chinese Journal of Applied Chemistry, 2001, 18(3): 246-0 |
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| Authors: | TENG Hong Xiang YING Lai Qiang HAN Shuang Cheng TANG Wen Hong BA Xiao Wei ZHAO Yu Ying LI Gang TANG Tao JIN Ying Tai |
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| Affiliation: | TENG Hong Xiang,YING Lai Qiang,HAN Shuang Cheng,TANG Wen Hong,BA Xiao Wei,ZHAO Yu Ying,LI Gang,TANG Tao,JIN Ying Tai * |
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| Abstract: | The polymerization of MMA catalyzed by bridged lanthanocene amide as single compoent catalyst has been investigated. The polymers obtained were characterized by GPC, FT IR, 1H NMR and DSC. The results indicated that the conversion and the molecular weight decreased with decrease in polymerization temperature. The PMMA obtained was mainly in syndiotactic structure. |
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| Keywords: | methyl methacrylate catalytic polymerization lanthanocene amide |
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