Synthesis, crystal structure and properties of a charge-transfer compound [(CH3)3CNH3]3[PMo12O40] · 2H2O |
| |
Authors: | Shen Lin Yan-Zhu Yea Xiao-Feng Zhang Chun-Lian Liu |
| |
Institution: | (1) College of Chemistry and Material Science, Fujian Normal University, Fuzhou, 350007, P.R. China;(2) Department of Chemistry and Life Sciences, Fujian Educational College, Fuzhou, 350001, P.R. China |
| |
Abstract: | A charge-transfer compound (CH3)3CNH3]3PMo12O40] · 2H2O was synthesized and characterized by IR, UV, ESR, diffusion reflectance electronic spectrum, cyclic voltammogram and X-ray
crystallography. Oxygen atoms of the polyoxometalate anion, N atoms of organic substrates (CH3)3CNH2 and O atoms of water molecules are involved in hydrogen bonding. The solid reflectance electronic spectra and IR data indicate
the presence of interaction between the PMo12O40]3− and the organic substrates in the solid state. Photosensitivity to ultraviolet light was assessed for the compound, showing
that charge-transfer resulted from oxidation of the organic substrates and the reduction of the heteropolyanion. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|