Tuning the adsorption and fluorescence properties of aminal‐linked porous organic polymers through N‐heterocyclic group decoration

Aiming at tuning the adsorption and fluorescence properties of targeted porous organic polymer, four new aminal‐linked porous organic polymers (NAPOPs) were synthesized through the reaction of 1,4‐Bis(4,6‐diamino‐s‐triazin‐2‐yl) benzene (BATB) with four kinds of aldehydes substituted with different N‐heterocyclic groups. Among the polymers, NAPOP‐3 decorated with 5‐phenyl‐tetrazole group shows the largest CO₂ adsorption capacity (2.52 mmol g^?1 at 273 K and 100 kPa) because of its relative large surface area, while NAPOP‐1 decorated with piperazine groups shows relative large CO₂/N₂ adsorption selectivity (77 at 273 K and 100 kPa), attributable to its large CO₂ adsorption heats and cabined pore (<4 Å). Meanwhile, NAPOP‐1 and ?3 exhibit high adsorption rate toward iodine with a high capacity (>240 wt %). In addition, different luminescence emissions were also observed for NAPOPs, indicating different intramolecular charger transfer occurred inside polymer networks. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1724–1730