On the determination of partial differential cross sections for photodetachment and photoionization processes producing polyatomic molecules with electronic states coupled by conical intersections

A formalism is derived for the computation of partial differential cross sections for electron photodetachment and photoionization processes that leave the residual or target molecule in electronic states that are strongly coupled by conical intersections. Because the electronic states of the target are nonadiabatically coupled, the standard adiabatic states approach of solving the electronic Schro?dinger equation for the detached electron at fixed nuclear geometries and then vibrationally averaging must be fundamentally modified. We use a Lippmann-Schwinger equation based approach, which leads naturally to a partitioning of the transition amplitude into a Dyson orbital like part plus a scattering correction. The requisite Green's function is that developed in our previous paper for the direct determination of total integral cross sections. The method takes proper account of electron exchange, possible nonorthogonality of the orbital describing the detached electron, and nonadiabatic effects in the product molecule. The Green's function is constructed in an L(2) basis using complex scaling techniques. The accurate treatment of nonadiabatic effects in the residual molecule is accomplished using the multimode vibronic coupling model. For photodetachment, an approximate approach, which is less computationally demanding, is suggested.