外电场下2,2’,5,5’-四氯联苯的分子结构与电子光谱

多氯联苯(PCBs)是难降解有机污染物, 2, 2’, 5, 5’-四氯联苯(PCB52)是PCBs的一种, 研究通过对PCB52分子加外电场的方法来降解该物质. 采用密度泛函B3LYP方法在6-311+g(d)基组水平上优化并计算了不同外电场(-0.04–0.04 a.u.)作用下PCB52的基态分子结构参数、分子总能量、电偶极矩和电荷分布. 然后利用含时密度泛函方法研究了PCB52分子在外电场下的前六个激发态的波长、激发能量和振子强度的影响. 结果表明: 随着外电场的增加, 1C–21Cl和14C–20Cl键的键长增大; PCB52的两个苯环在外加电场下, 二面角增大, 分子毒性减弱; PCB52分子能隙减小, 导致分子更容易受激发而跃迁到激发态发生还原脱氯反应. 外电场的增大, 激发态的激发能在迅速减小, 吸收波长也迅速红移, 振子强度不再为零. 表明电场作用下, 分子易于激发和解离.关键词：2,2’,5,5’-四氯联苯电场基态激发特性

Molecular structure and electronic spectrum of 2, 2’, 5, 5’-tetrachlorobiphenyl under the extenal electric field

Polychlorinated biphenyls (PCBs) are persistent organic pollutant, and 2, 2’, 5, 5’-tetrachlorobiphenyl is generally used as a model molecule of PCBs in some studies. PCB52 molecule is degraded under external electric fields. The molecular structure of PCB ground state is optimized by density functional theory (B3LYP) method with 6-311+g(d) basis sets. The effects of electric fields ranging from-0.04 a.u. to 0.04 a.u. are investigated on structural parameters, total energy, dipole moment and charges distribution. The transition wavelengths, oscillator strengths and excitation energies of the first six excited states under external electric fields are calculated by the time dependent density functional theory method. The result shows that the bond lengths of 1C–21Cl and 14C–20Cl increase with external electric field increasing. The dihedral angle of two benzene rings of PCB52 molecule increases under the electric fields, and the PCB52 molecule reduces toxicity. PCB52 molecule energy gaps decrease, leading to the fact that the molecule is susceptible to excitation to an excited state and reductive dechlorination reaction. As the increase of the applied electric field, the excitation energies rapidly decrease, absorption wavelengths are red-shifted toward longer wavelength and oscillator strength is no longer zero, which indicates that the PCB52 molecule is easily excited and dissociated.
Keywords：2,2’,5,5’-tetrachlorobiphenylelectric fieldground statesexcitation properties