Synthesis,structure and characterization of some Schiff bases bearing phenylferrocene |
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Authors: | Faiz Ullah Shah Zareen Akhter Humaira M Siddiqi Masood Parvez |
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Institution: | 1. Department of Chemistry, Quaid‐i‐Azam University, Islamabad‐45320, Pakistan;2. Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4 |
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Abstract: | Some novel Schiff bases bearing phenylferrocene were synthesized by condensation reaction of 4‐ferrocenylaniline with different aromatic aldehydes. The compounds prepared were characterized by spectroscopic methods (IR, UV–visible, 1H and 13C NMR) and elemental analysis. The single crystal analysis of compound F1 monoclinic, space group, P21/c (no. 14), a = 19.858(2), b = 7.416(2), c = 12.095(5) Å, β = 106.257(14) ] indicates a trans imine bond with a bond length of 1.270(2) Å, typical of a carbon‐nitrogen double bond. Copyright © 2007 John Wiley & Sons, Ltd. |
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Keywords: | ferrocene Schiff bases phenylferrocene |
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