Preparation,characterization and catalytic oxidation properties of bis‐quaternary ammonium peroxotungstates and peroxomolybdates complexes |
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| Authors: | Xianying Shi Junfa Wei |
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| Affiliation: | School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an, People's Republic of China |
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| Abstract: | Several novel kinds of bis‐quaternary ammonium peroxotungstates and peroxomolybdates, such as PhCH2N(CH2CH2)3NCH2Ph[W2O3(O2)4], PhCH2N(CH2CH2)3NCH2Ph [Mo2O3(O2)4], [PhCH2(CH3)2NCH2]2[W2O3(O2)4] and [PhCH2(CH3)2NCH2]2[Mo2O3(O2)4], have been synthesized and characterized by elemental analysis, IR and Raman spectroscopy. Their catalytic properties in mild oxidation of benzyl alcohol and ring‐substituted benzyl alcohols were investigated with aqueous 30% H2O2 under halide‐ and organic solvent‐free conditions. Copyright © 2007 John Wiley & Sons, Ltd. |
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| Keywords: | peroxotungstate peroxomolybadate bis‐quaternary ammonium clean oxidation hydrogen peroxide |
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