Some addition reactions of bisgermavinylidene |
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| Authors: | Wing‐Por Leung Kwok‐Wai Kan Cheuk‐Wai So Thomas C W Mak |
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| Institution: | Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, People's Republic of China |
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| Abstract: | The reaction of bisgermavinylidene (Me3SiN?PPh2)2C?Ge→Ge?C(PPh2?NSiMe3)2] ( 1 ) with AdNCO (Ad = Adamantyl) afforded the 2 + 2] cycloadditon product (Me3SiN?PPh2)2CGeC(O) NAd] ( 2 ). Similar reaction of 1 with Ph3SiOH in tetrahydrofuran (THF) yielded the base‐stabilized germanium(II) triphenylsiloxide H2C(PPh2?NSiMe3)2Ge(OSiPh3)2] ( 3 ). The results suggested that reactive germavinylidene may exist in solution and is capable of forming addition reaction products. The X‐ray structures of 2 and 3 were determined. Copyright © 2007 John Wiley & Sons, Ltd. |
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| Keywords: | germanium germene cycloaddition germavinylidene |
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