Remarkable solvent effects in the hydro‐ and solvothermal synthesis of copper‐1,10‐phenanthroline complexes |
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| Authors: | Xiong‐Bin Chen Bin Chen Yi‐Zhi Li Xiao‐Zeng You |
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| Institution: | 1. Department of Chemistry, Science College, Tianjin University, Tianjin 300072, People's Republic of China;2. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China |
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| Abstract: | Compound {Cu(II)/Cu(I)]2(ophen)4(Htpt)}?2H2O ( 1 ) was obtained by hydrothermal reaction. Compound 1 is a mixed‐valence copper coordination complex with a different coordination environment. The X‐ray structural analysis of 1 revealed two crystallographically independent dimeric Cu2(ophen)2]+ units bridged by two µ1‐carboxylate groups of the tpt ligand into a butterfly‐shaped molecule in the crystal structure. Compound Cu(I)3(CN)3(phen)3] ( 2 ) was synthesized using ethanol instead of water, and consisted of an infinite helix chain formed from Cu(I)(phen)]+ units bridged by cyano groups. Copyright © 2007 John Wiley & Sons, Ltd. |
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| Keywords: | hydrothermal reaction mixed‐valence redox solvent effects |
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