Organometallic synthesis in the furazan series. 4. Reactions of azofurazans with organolithium compounds |
| |
| Authors: | A. B. Sheremetev,E. A. Ivanova,E. V. Shatunova,D. E. Dmitriev,N. E. Kuz" mina |
| |
| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation |
| |
| Abstract: | The reactions of azofurazans, including macrocyclic azofurazans, with BunLi and Li derivatives of methylfurazans were studied. Several competitive processes were found to occur: the addition of a Li reagent at the N=N bond, the redox reaction giving rise to hydrazofurazans, and the reaction of the side chain of azofurazan. |
| |
| Keywords: | azofurazans organolithium compounds electrophilic addition redox reaction X-ray diffraction study |
| 本文献已被 SpringerLink 等数据库收录！ |
|
