The equivalence of ensembles for classical systems of particles |
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Authors: | Hans-Otto Georgii |
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Affiliation: | (1) Mathematisches Institut der Universität Munich, Germany |
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Abstract: | For systems of particles in classical phase space with standard Hamiltonian, we consider (spatially averaged) microcanonical Gibbs distributions in finite boxes. We show that infinite-volume limits along suitable subsequences exist and are grand canonical Gibbs measures. On the way, we establish a variational formula for the thermodynamic entropy density, as well as a variational characterization of grand canonical Gibbs measures. |
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Keywords: | Classical statistical mechanics microcanonical ensemble variational principle entropy pressure |
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