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The equivalence of ensembles for classical systems of particles
Authors:Hans-Otto Georgii
Affiliation:(1) Mathematisches Institut der Universität Munich, Germany
Abstract:For systems of particles in classical phase space with standard Hamiltonian, we consider (spatially averaged) microcanonical Gibbs distributions in finite boxes. We show that infinite-volume limits along suitable subsequences exist and are grand canonical Gibbs measures. On the way, we establish a variational formula for the thermodynamic entropy density, as well as a variational characterization of grand canonical Gibbs measures.
Keywords:Classical statistical mechanics  microcanonical ensemble  variational principle  entropy  pressure
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