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Great improvement of low‐temperature impact resistance of isotactic polypropylene/ethylene propylene diene monomer rubber blends by traces of carbon nanotubes and β‐nucleating agents
Authors:Qian Fan  Jinghan Zhang  Zhiqiang Wu  Song Yang  Yanhui Chen  Ying Lu  Qiuyu Zhang
Abstract:In this work, a considerable low‐temperature toughness enhancement of isotactic polypropylene (iPP) was achieved by adding 30 wt% ethylene propylene diene monomer rubber (EPDM) as well as traces of β‐nucleating agent (β‐NAs) and carbon nanotubes (CNTs). The impact strength of the iPP/30 wt% EPDM blend with 0.1 wt% β‐NAs reached 6.57 kJ/m2 at ?20°C, over 2.5 times of pure iPP. A slightly improved impact strength was further found in the β‐nucleated iPP/30 wt% EPDM at the presence of 0.05 wt% CNTs. The presence of traces of CNTs, β‐NAs, and EPDM displayed synergistic low‐temperature toughness reinforcement effect on the iPP blends. The underlying toughening mechanism was attributed to the formation of a great amount of voids and plastic deformation of iPP matrix affected by CNTs, β‐NAs, and EPDM. Our work provided a feasible strategy to significantly increase the low‐temperature toughness of iPP.
Keywords:β  ‐nucleating agent  carbon nanotubes  ethylene propylene diene monomer rubber  impact strength  isotactic polypropylene
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