| 摘 要： | Two new hydrogen storage compounds,Na Zn(BH_4)_3·en and Na Zn(BH_4)_3·2en(en=ethylene diamine)are synthesized by a solution method.They can release 6.4 wt% and 6.3 wt% pure hydrogen below 200℃,respectively,demonstrating the potential to be used as hydrogen carriers.Additionally,their dehydrogenation products,thermodynamics and kinetics are well characterized and analyzed.Results shows that the stronger Zn-N interactions and the Hδ~+–Hδ~- interactions are significant for their stability below 100℃,relatively low decomposition temperatures and elimination of gas impurities.
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