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Analytical theory of ideal polydisperse polymers at interfaces
Authors:Woodward Clifford E  Forsman Jan
Affiliation:School of Physical, Environmental and Mathematical Sciences, University College, University of New South Wales, ADFA, Canberra, ACT, Australia. c.woodward@adfa.edu.au
Abstract:We use a recently developed continuum theory to present an exact treatment of the interfacial properties of ideal polymers displaying Schulz-Flory polydispersity. Our results are remarkably compact and can be derived from the properties of equilibrium, ideal polymers at interfaces. We apply our theory to a number of cases, including, non-adsorbing and adsorbing surfaces, as well as telechelic chains.
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