A novel approach for the separation of neutral analytes by means of electrochemically assisted injection coupled to capillary electrophoresis-mass spectrometry |
| |
Authors: | Scholz Rebekka Matysik Frank-Michael |
| |
Institution: | Institute of Analytical Chemistry, Chemo- and Biosensors, University of Regensburg, Regensburg, Germany. |
| |
Abstract: | A novel concept for capillary electrophoresis-mass spectrometry (CE-MS) studies of neutral analytes is presented. The experimental approach is based on the implementation of electrochemically assisted injection (EAI) which enables the generation of charged species from neutral analytes. In this way electrophoretic separations can be performed without the use of surfactants leading to an excellent compatibility with ESI-MS. Various ferrocene species have been used as model compounds to demonstrate the potential of the EAI-CE-MS technique. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|