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Excited-state annihilation in a homodinuclear ruthenium complex
Authors:Kuhnt Christian  Karnahl Michael  Schmitt Michael  Rau Sven  Dietzek Benjamin  Popp Jürgen
Affiliation:Institute for Physical Chemistry, Friedrich-Schiller-University Jena, Jena Center of Soft Matter and Abbe Center of Photonics, Helmhotzweg 4, 07743 Jena, Germany.
Abstract:Ultrafast excited-state annihilation in a homodinuclear ruthenium complex is observed. This coordination compound constitutes a model system for approaches towards artificial photosynthetic systems. The observation of pump-intensity dependent triplet-triplet annihilation highlights the importance of considering various loss mechanisms in the design of artificial photosynthetic assemblies.
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