Analysis of the metal-catalyzed decomposition of γ- and δ-haloesters by GC/FT-IR |
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Authors: | D. E. Henry S. L. Pentoney Jr. R. W. Kondrat P. R. Griffiths |
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Affiliation: | (1) Department of Chemistry, University of California, 92521 Riverside, CA, USA |
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Abstract: | Summary The decomposition of γ- and δ-haloesters has previously been observed to take place within a commercial GC/FT-IR light-pipe system. Using a home-built light-pipe interface, an analysis of this same class of compounds was conducted from which the source of the decomposition was determined to be a brass fitting central to the commercial system's assembly. It is proposed that the reaction is due to a weakening of the carbon-halogen bond by metal interaction thereby allowing lactonization to occur. |
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Keywords: | Gas chromatography FT-IR detection γ - and δ -Haloesters |
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