ELECTRONIC SPECTRA AND STRUCTURE OF PHRIDINUM HYDROGEN DI-μ-OXO-BIS(OXO-(OXALATO)AQUOMOLYBDATE(V))~(2-) ANION

<正> Introduction. Some active enzymes in nature contain Mo element. It has been shown by the experiments that Mo atoms in Mo enzYmes exist probably in dinucleus species with (V) or (VI) oxidational states. Therefore, the coordination chemistry of high-valency Mo compounds has attracted wide attention among which one is di-μ-oxo-dimolybdenum compound. The spectral property of the compounds containing (Mo_2O_4(C_2O_4)_2(H_2O)_2)~2- anion has been studied~(3,4).

ELECTRONIC SPECTRA AND STRUCTURE OF PHRIDINUM HYDROGEN DI-μ-OXO-BIS(OXO-(OXALATO)AQUOMOLYBDATE(V))~(2-) ANION