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求等价电子组态j—j偶合谱项的J值
引用本文:宋克敏,常光洁.求等价电子组态j—j偶合谱项的J值[J].光谱学与光谱分析,1993,13(6):13-17.
作者姓名:宋克敏  常光洁
作者单位:河北教育学院,河北师范大学化学系,河北教育学院,河北教育学院 050091 石家庄,050016 石家庄,050091 石家庄,050091 石家庄
摘    要:j-j偶合方法对研究重核原子的光谱十分重要,然而对于复杂的等价组态用人工推求其j-j偶合谱项已经不可能,其难点在于求j-j偶合谱项总的J值。在这篇论文中,我们提出了推求该类谱项J值的简单方法,利用PASCAL语言编制了计算程序,利用本程序可求出各种等价电子组态j-j偶合谱项的J值,使求取j-j偶合谱项的工作变得方便、快速、准确。

关 键 词:原子谱项  j-j偶合  等价电子组态

FINDING THE ALLOWED VALUES OF J IN j-j COUPLING OF EQUIVALENT ELECTRONS
SONG Kemin Hebei Educational College, Shijiazhuang,Hebei CHANG Guangjie.FINDING THE ALLOWED VALUES OF J IN j-j COUPLING OF EQUIVALENT ELECTRONS[J].Spectroscopy and Spectral Analysis,1993,13(6):13-17.
Authors:SONG Kemin Hebei Educational College  Shijiazhuang  Hebei CHANG Guangjie
Institution:SONG Kemin Hebei Educational College,050091 Shijiazhuang,Hebei CHANG Guangjie Department of Chemistry,Hebei Normal University,050016 Shijiazhuang,Hebei NIE Wujun Hebei Educational College,050091 Shijiazhuang,Hebei FENG Yuling Hebei Educationl College,050091 Shijiazhuang,Hebei
Abstract:A simple method is given to find the values of the total angular momentum J for configuration of equivalent electrons in j-j coupling and a calculating program is worked out. By using the program, we can find the allowed values of J in j-j coupling of equivalent electrons and so that the derivation of atomic spectral terms in j-j coupling of equivalent configuration is convenient, quick and accurate.
Keywords:Equivalent configuration  Atomic spectral terms  j-j coupling
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