|
|||||
|
|
Electrooxidation of tigogenin acetate |
|
| Authors: | Jacek W Morzycki Yliana Lpez Jolanta P&#x;oszy&#x;ska Rosa Santillan Leszek Siergiejczyk Andrzej Sobkowiak |
| Institution: | aInstitute of Chemistry, University of Białystok, Piłsudskiego 11/4, 15-443 Białystok, Poland;bFaculty of Chemistry, Rzeszów University of Technology, P.O. Box 85, 35-959 Rzeszów, Poland;cDepartamento de Química, CINVESTAV-IPN, Apdo. Postal 14-740, 07000 Mexico, D.F., Mexico |
| Abstract: | Electrooxidation of tigogenin acetate afforded two products: 3β-acetoxy-16β-hydroxy-23,24-dinor-5α-cholanoic acid lactone (2) and 20-epitigogenin acetate (3). The structure of the latter compound was confirmed by an X-ray analysis. The tentative mechanism of reaction is proposed. |
| Keywords: | Saponins Tigogenin Electrochemical oxidation Electrochemically-induced stereoisomerization |
| 本文献已被 ScienceDirect 等数据库收录！ | |