Enantioselective total synthesis of (-)-xialenon A |
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| Authors: | Hodgson David M Galano Jean-Marie Christlieb Martin |
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| Affiliation: | Dyson Perrins Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK OX1 3QY. david.hodgson@chem.ox.ac.uk |
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| Abstract: | The first total synthesis of (-)-xialenon A (1) via conjugate allylation of a 1,5-cyclooctadiene-derived bicyclo[3.3.0]octenone 3 and an alpha'-hydroxylation on the more hinderd face of enone 9 using hypervalent iodine chemistry, is described. |
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