Synthesis of (+)-puraquinonic acid |
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Authors: | Clive Derrick L J Yu Maolin |
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Institution: | Chemistry Department, University of Alberta, Edmonton, Alberta, Canada T6G 2G2. |
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Abstract: | (+)-Puraquinonic acid (1a) was synthesized, using a route based on ring-closing metathesis and radical cyclization, the chirality of the quaternary carbon being controlled by a temporary adjacent asymmetric center. |
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