Characterization of the active sites in MgNiAl mixed oxides by microcalorimetry and test reaction |
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Authors: | D. Meloni M. F. Sini M. G. Cutrufello R. Monaci E. Rombi I. Ferino |
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Affiliation: | 1. Dipartimento di Scienze Chimiche, Università di Cagliari, Complesso Universitario Monserrato, s.s. 554, Bivio Sestu, 09042, Monserrato, CA, Italy
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Abstract: | In this study, MgNiAl mixed oxides derived from layered double hydroxide precursors were prepared by pH-controlled co-precipitation. Three samples were prepared with a (Mg2+ + Ni2+)/Al3+ ratio of 2 and a Ni2+/Mg2+ with ratios of 0.22, 0.47, and 4.05. The structural, textural and redox features of the oxides were investigated by a variety of techniques, including X-ray diffraction, transmission electron microscopy, N2 physisorption, and temperature-programmed reduction. The acid and base properties were assessed by NH3 and CO2 adsorption microcalorimetry, respectively. The acid–base features were also investigated by testing the catalytic behaviors of the oxides for the conversion of 4-methylpentan-2-ol under both mild and stressed conditions. The reactant alcohol can undergo dehydration into 4-methylpent-1-ene, 4-methylpent-2-ene, and skeletal isomers of C6-alkenes, as well as dehydrogenation to 4-methylpentan-2-one and higher ketones, the product selectivity being governed by the concentration and strength of the acid and base sites. Comparison between the calorimetric and test reaction results is discussed. |
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