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Pressure and temperature variation of the depolarized light scattering spectra of the fragile glass-former liquid salol
Authors:G Pratesi  A Bellosi  F Barocchi
Institution:(1) Istituto Nazionale per la Fisica della Materia, L.go E. Fermi 2, 50125, Florence, Italy, IT;(2) Universitá di Firenze, L.go E. Fermi 2, 50125, Florence, Italy, IT;(3) Laboratorio Europeo di Spettroscopia Nonlineare, L.go E. Fermi 2, 50125, Florence, Italy, IT
Abstract:The pressure and temperature dependences of the depolarized light scattering spectra of salol have been measured at isobaric condition P = 1 bar for T between 328 and 393 K, and at isothermal condition T = 343 K for P between 1 and 625 bar, i.e. outside the metastable liquid region. The experimental results for both the α- and β-relaxations can be well described by the Mode Coupling Theory. The independence of the power-law parameters a, and consequently b and γ, from the thermodynamic variables T and P is demonstrated.The critical temperature T c at 1 bar and the critical pressure P c at T = 343 K have been determined from the normal liquid state. Received 2 May 2000
Keywords:PACS  64  70  Pf Glass transitions - 07  35  +k High-pressure apparatus and techniques  shock tubes  diamond anvil cells - 78  35  +c          Brillouin and Rayleigh scattering  other light scattering
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