Computational and experimental study of oxygen-enhanced axisymmetric laminar methane flames

Three axisymmetric laminar coflow diffusion flames, one of which is a nitrogen-diluted methane/air flame (the ‘base case’) and the other two of which consist of nitrogen-diluted methane vs. pure oxygen, are examined both computationally and experimentally. Computationally, the local rectangular refinement method is used to solve the fully coupled nonlinear conservation equations on solution-adaptive grids. The model includes C2 chemistry (GRI 2.11 and GRI 3.0 chemical mechanisms), detailed transport, and optically thin radiation. Because two of the flames are attached to the burner, thermal boundary conditions at the burner surface are constructed from smoothed functional fits to temperature measurements. Experimentally, Raman scattering is used to measure temperature and major species concentrations as functions of the radial coordinate at various axial positions. As compared to the base case flame, which is lifted, the two oxygen-enhanced flames are shorter, hotter, and attached to the burner. Computational and experimental flame lengths show excellent agreement, as do the maximum centreline temperatures. For each flame, radial profiles of temperature and major species also show excellent agreement between computations and experiments, when plotted at fixed values of a dimensionless axial coordinate. Computational results indicate peak NO levels in the oxygen-enhanced flames to be very high. The majority of the NO in these flames is shown to be produced via the thermal route, whereas prompt NO dominates for the base case flame.