Uncertainty quantification in the catalytic partial oxidation of methane |
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Authors: | Jorge E.P. Navalho José M.C. Pereira Ana R. Ervilha |
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Affiliation: | Universidade Técnica de Lisboa, Instituto Superior Técnico, Mechanical Engineering DepartmentLASEF,, Lisbon, Portugal, 1049-001 |
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Abstract: | This work focuses on uncertainty quantification of eight random parameters required as input for 1D modelling of methane catalytic partial oxidation within a highly dense foam reactor. Parameters related to geometrical properties, reactor thermophysics and catalyst loading are taken as uncertain. A widely applied 1D heterogeneous mathematical model that accounts for proper transport and surface chemistry steps is considered for the evaluation of deterministic samples. The non-intrusive spectral projection approach based on polynomial chaos expansion is applied to determine the stochastic temperature and species profiles along the reactor axial direction as well as their ensemble mean and error bars with a confidence interval of 95%. Probability density functions of relevant variables in specific reactor sections are also analysed. A different contribution is noticed from each random input to the total uncertainty range. Porosity, specific surface area and catalyst loading appear as the major sources of uncertainty to bulk gas and surface temperature and species molar profiles. Porosity and the mean pore diameter have an important impact on the pressure drop along the whole reactor as expected. It is also concluded that any trace of uncertainty in the eight input random variables can be almost dissipated near the catalyst outlet section for a long-enough catalyst, mainly due to the approximation to thermodynamic equilibrium. |
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Keywords: | catalytic partial oxidation parametric uncertainty quantification non-intrusive spectral projection polynomial chaos syngas |
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