Reactions ofN-pentafluorophenylcarbonimidoyl dichloride with aromatic hydrocarbons in the presence of aluminum chloride期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Reactions ofN-pentafluorophenylcarbonimidoyl dichloride with aromatic hydrocarbons in the presence of aluminum chloride

Authors:	T D Petrova I V Kolesnikova V I Mamatyuk V P Vetchinov V E Platonov I Yu Bagryanskaya Yu V Gatilov

Institution:	(1) Siberian Branch of the Russian Academy of Sciences, Novosibirsk Institute of Organic Chemistry, 9 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation

Abstract:	N-Pentafluorophenylcarbonimidoyl dichloride reacts with aromatic hydrocarbons (benzene, toluene, xylenes, and mesitylene) in the presence of AlCl₃ to give stableN-pentafluorophenylbenzimidoyl chlorides, which can further react with aromatic hydrocarbons to give azomethine derivatives. An increase in the number of methyl groups in the molecule of a hydrocarbon favors the reaction.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1605–1611, September, 1993.

Keywords:	aluminum chloride aromatic hydrocarbons N-pentafluorophenylcarbonimidoyl dichloride polyfluoroaromatic imidoyl chlorides azomethines
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