Towards the Design of New Materials: Regio- and Stereoselective (Cyclo-) Polymerization of 1-Alkynes and 1,6-Heptadiynes |
| |
Authors: | Michael R Buchmeiser |
| |
Institution: | (1) Arbeitskreis Makromolekulare Chemie, Institut für Analytische Chemie und Radiochemie, Leopold-Franzens-Universit?t Innsbruck, A-6020 Innsbruck, Austria, AT |
| |
Abstract: | Summary. The metathesis polymerization, respectively cyclopolymerization, of 1-alkynes and 1,6-heptadiynes using well-defined group
VIA transition metal initiators is summarized. For purposes of comparison, selected quaternary catalytic systems used as alternatives
as well as the properties of the resulting materials will be presented. Special consideration is given to the mechanistic
advancements that have been made during the last decade, which allow the tailor-made synthesis of conjugated materials with
interesting optical and electronic properties.
E-mail: michael.r.buchmeiser@uibk.ac.at
Received November 20, 2002; accepted November 21, 2002 |
| |
Keywords: | , Metathesis, Polymerizations, Metallocenes, Organometallics, Homogeneous catalysis, |
本文献已被 SpringerLink 等数据库收录! |
|