| One-step Beckmann Rearrangement from Ketones and Hydroxylamine in Dry Media under Microwave Irradiation |
| |
| 引用本文： | Jun Cai FENG, Bin LIU, Li DAI, Ning Sheng BIAN (Department of Chemistry,Nanjing University,Naning 210093). One-step Beckmann Rearrangement from Ketones and Hydroxylamine in Dry Media under Microwave Irradiation[J]. 中国化学快报, 1998, 0(9) |
| |
| 作者姓名： | Jun Cai FENG Bin LIU Li DAI Ning Sheng BIAN (Department of Chemistry Nanjing University Naning 210093) |
| |
| 作者单位： | Department of Chemistry，Nanjing University，Naning 210093 |
| |
| 摘 要： | TheBeckInannrearrangement,theacid-mediatedisomerizationofoximestoamides,wasfirstdiscoveredinl886l.Asoneoftheoldestandmostfamiliartransformationsinorganicchemistry,ithasbeenwidelystudiedandagreatvarietyofmethodstoconductthistfansformationhavebeenreported'.However,mostofthesemethodswerecarriedoutbyusingalargeamountofsolventswithlongreactiontime.Whatismore,thepriorpreparationofthecorrespondingketoximesisusuallyrequired,whichmakestheseprocessesinconvenientandlessattractive.Bytakingadvantageofboth…
|
One-step Beckmann Rearrangement from Ketones and Hydroxylamine in Dry Media under Microwave Irradiation |
| |
| Jun Cai FENG, Bin LIU, Li DAI, Ning Sheng BIAN. One-step Beckmann Rearrangement from Ketones and Hydroxylamine in Dry Media under Microwave Irradiation[J]. Chinese Chemical Letters, 1998, 0(9) |
| |
| Authors: | Jun Cai FENG Bin LIU Li DAI Ning Sheng BIAN |
| |
| Abstract: | Ketones react with hydroxylamine hydrochloride over HCOOH/SiO2 under ndcrowaveirradiation to afford anddes in good yields. |
| |
| Keywords: | Beckmann rearrangement microwave irradiation |
| 本文献已被 CNKI 等数据库收录！ |
