首页 | 本学科首页   官方微博 | 高级检索  
     检索      


The effect of recrystallization time on pore size and surface area of mesoporous SBA-15
Authors:Ephraim Vunain  Rehana Malgas-Enus  Kalala Jalama  Reinout Meijboom
Institution:1. Department of Chemistry, Research Centre for Synthesis and Catalysis, University of Johannesburg, P. O. Box 524, Auckland Park, Johannesburg, 2006, South Africa
2. Department of Chemical Engineering, University of Johannesburg, Doornfontein Campus, P. O. Box 17011, Doornfontein, Johannesburg, 2028, South Africa
Abstract:Triblock copolymer, pluronic P123 (EO20PO70EO20) was used as the structure directing agent for the simple synthesis and characterization of mesoporous SBA-15 with various porosities. Extending the sample recrystallization time, after the initial synthesis and ageing, seems to have a significant effect on the pore size. It also leads to an increase in the surface area and a narrow pore size distribution. The prepared materials could find applications in areas where the diffusion of large molecules is important, and in catalysis, where greater pore accessibility would enhance the activity and selectivity of the catalyst. A possible mechanism has been proposed to describe the effect of extended recrystallization on pore sizes.
Keywords:
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号