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Ruthenium-catalyzed 1,3-dipolar cycloaddition of trifluoromethylated propargylic alcohols with azides |
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| Authors: | Chun-Tao Zhang Xingang Zhang Feng-Ling Qing |
| Affiliation: | aCollege of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Road, Shanghai 201620, China bLaboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China |
| Abstract: | The 1,3-dipolar cycloaddition of trifluoromethylated propargylic alcohols 1 with azides in the presence of catalytic [Cp*RuCl2]n afforded exclusively 4-trifluoromethyl-1,4,5-trisubstituted-1,2,3-triazoles 2 in high yields. |
| Keywords: | 1,3-Dipolar cycloaddition Triazole Trifluoromethylated compound |
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