Rotation Part of the Dielectric Permittivity of Water Vapor for Different Spectral Line Profiles

We estimate the possible influence of spectral line profile (Lorentz profile, Van Vleck–Weisskopf profile, and profile obtained by solving kinetic equation) on the rotation part of the dielectric permittivity of water-vapor monomers. Spectral regions corresponding to long-wavelength (static) and high-frequency (optical) limiting cases as well as regions in close proximity to resonances of various intensities are considered. The studied effects are compared with the corresponding effects on water-vapor absorption coefficient, which are related to factors determining the line-shape structure.