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Chemoselective hydrogenation of nitroarenes with carbon nanofiber-supported platinum and palladium nanoparticles
Authors:Takasaki Mikihiro  Motoyama Yukihiro  Higashi Kenji  Yoon Seong-Ho  Mochida Isao  Nagashima Hideo
Institution:Graduate School of Engineering Sciences, Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan.
Abstract:Platinum and palladium nanoparticles supported on three types of carbon nanofibers (CNFs) are synthesized and used as catalysts in the hydrogenation of nitroarenes. Nanosized platinum particles dispersed on platelet-type CNF efficiently catalyze the reduction of functionalized nitroarenes to the corresponding substituted anilines in high turnover numbers with other functional groups remaining intact.
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