Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters |
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| Authors: | Oestreich Martin Sempere-Culler Fernando |
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| Affiliation: | Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universit?t, Albertstrasse 21, D-79104 Freiburg im Breisgau, Germany. martin.oestreich@orgmail.chemie.uni-freiburg.de |
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| Abstract: | Regio- and diastereoselective preparation of bishomoallylic alcohols was realized by a facile four-step protocol including alpha,alpha'-selective zinc-mediated bispropargylation of unactivated esters and stereoselective reduction of the resulting bishomopropargylic alcohols. |
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