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Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(II) complexes: the role of the exo anomeric effect |
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| Authors: | Khiar Noureddine Araujo Cristina S Suárez Bélen Alvarez Eleuterio Fernández Inmaculada |
| Institution: | Instituto de Investigaciones Químicas, C.S.I.C-Universidad de Sevilla, c/. Américo Vespucio, s/n., Isla de la Cartuja, 41092 Seville, Spain. khiar@cica.es |
| Abstract: | Treatment of several C(2) symmetric bis-thioglycosides with Pd(CH(3)CN)(2)Cl(2) always leads to a single diastereomeric Pd(II) complex as a consequence of the exo-anomeric effect. |
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