Reactivity of beta-lactamido N-sulfonyl radicals |
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| Authors: | Montermini Florian Lacôte Emmanuel Malacria Max |
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| Institution: | Laboratoire de Chimie Organique, UMR CNRS 7611, Université Pierre et Marie Curie, Case 229, 4 Place Jussieu, 75005 Paris, France. |
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| Abstract: | reaction: see text] A new class of N-substituted radical has been studied. Obtained from the corresponding chlorides, beta-lactamido N-sulfonyl radicals were allylated and added onto electron-rich olefins. It has been shown that the radicals do not undergo desulfonylation and are electrophilic in nature. |
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