Kinetics of dimethyldioxirane decomposition in the presence of cumene |
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| Authors: | D V Kazakov N N Kabalnova S L Khursan S A Grabovsky and V V Shereshovets |
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| Institution: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, prospekt Oktyabrya 71, 450054 Ufa, Russia |
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| Abstract: | Dimethyldioxirane consumption increases considerably in the presence of cumene. The product composition (cumic alcohol, acetophenone,
α-methylstyrene) and the inhibiting effect of oxygen prove a radical reaction mechanism. The kinetic order for dimethyldioxirane
increases with the conversion from 1.5 to 2. |
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| Keywords: | Dimethyldioxirane cumene radical-chain process |
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