Synthesis and Structure of a Copper Complex of a Macrocyclic Ligand with Dissimilar HN+N(Amino)O2 and N2(Imino)O2 Inners |
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| Authors: | Tamboura Farba Bouyagui Gaye Mohamed Nedelec Jean Marie Mentre Olivier |
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| Institution: | (1) Faculté des Sciences et Techniques, Département de Chimie, Université Cheikh Anta Diop, Dakar, Senegal;(2) Laboratoire des Matériaux Inorganiques UMR CNRS 6002, Université Blaise Pascal, 24 Avenue des Landais 63177, Aubere Cedex, France;(3) Laboratoire de Cristallochimie et Physico-chimie du Solide CNRS UMR 8012, Université des Sciences et Technologies de Lille, 59652 Villeneuve D’Ascq Cedex, France |
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| Abstract: | Abstract The copper complex Cu(C23H27Br2N4O2)(H2O)(NO3)]2 was synthesized and characterized by X-ray diffraction. The complex crystallizes in the triclinic system with space group
P-1, lattice parameters: a = 13.2293(18) (?), b = 14.184(20) (?), c = 16.522(23) (?), α = 91.923(2)°, β = 111.777(2)°, γ = 111.259(2)°, V = 2632.0(6) ?3, Z = 4, D
c
= 0.88 Mg m−3. In the title compound Cu(C23H27Br2N4O2)(H2O)(NO3)]2, the coordination polyhedron of the Cu atom is a square-planar environment. The structure consists of mononuclear units in
which the copper(II) ions are linked in the plane by N, N′ iminato and O, O′ phenoxo atoms. In addition the crystal lattice
contains one water molecule per unit.
Graphical Abstract Dissymmetric ligand was efficiently synthesized and used to prepfsare a copper(II) complex which was characterized by X-ray
diffraction
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| Keywords: | Imine Copper Crystal structure |
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