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Trip2C6H3SeF: the first isolated selenenyl fluoride |
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| Authors: | Poleschner Helmut Ellrodt Stefan Malischewski Moritz Nakatsuji Jun-ya Rohner Christian Seppelt Konrad |
| Affiliation: | 1. Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universit?t Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany);2. Department of Chemistry, Graduate School of Science, Hiroshima University, 1‐3‐1 Kagamiyama, Higashi‐Hiroshima, 739‐8526 (Japan);3. Institut für Anorganische und Analytische Chemie, Justus‐Liebig‐Universit?t Gie?en, Heinrich‐Buff‐Ring 58, 35392 Gie?en (Germany) |
| Abstract: | Joining the stable: The first examples of the highly instable selenenyl fluorides RSeF are prepared from the reaction on the tin selenide RSeSnMe(3) with XeF(2). Through the use of extremely large protecting groups (m-terphenyl ligands) which stabilizes the RSeF units against disproportionation, the compounds could be isolated and characterized by NMR spectroscopy and single-crystal structure analysis (see structure). |
| Keywords: | ab initio calculations fluorine selenium structure elucidation tellurium |
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