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Synthesis and structure ofexo-11-cyano-endo-11-(trimethylsilyloxy)pentacyclo[5.4.0.02,6.03,10.05,9]undecan-8-one
Authors:Simon G. Bott  Alan P. Marchand  D. Vidyanand  Richard A. Sachleben
Affiliation:(1) Department of Chemistry, University of North Texas, 76203 Denton, Texas;(2) Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, 37831 Oak Ridge, Tennessee
Abstract:The crystal structure of an asymmetric pentacyclo[5.4.0.02,6.03,10.05,9]undecan-8,11-dione derivative is reported, in which Me3SiCN has been added across one of the keto groups. The cage structure demonstrates the expected effects of this addition.
Keywords:Crystal structure  pentacycloundecan-8-one  pentacycloundecane-8,11-dione
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