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A Study on a Partially Immersed Gold Electrode Using an Electrochemical Quartz Crystal Impedance System
作者姓名:Qing Ji XIE  You Yu ZHANG  Ming SUN  Ling YI  Shou Zhuo YAO Chemical Research Institute  Hunan Normal University  Changsha
作者单位:Qing Ji XIE; You Yu ZHANG; Ming SUN; Ling YI; Shou Zhuo YAO Chemical Research Institute,Hunan Normal University,Changsha 410081
基金项目:This work was supported by the National Natural Science Foundation of China,the Science and Technology Foundation of Hunan P
摘    要:Simultaneous and fast measurement of the piezoelectric quartz crystal (PQC) impedanceduring electrochemical pertUrbations, i.e., the electrochemical quartz crystal impedancesystem (EQCIS) called by us, characterizes the PQC resonance better by providingmultidimensional in sl'tu piezoelectric information than the conventional electrochemicalquartz crystal microbalance (EQCM)'-'. The PQC impedance has been analyzed basedon the Butterworth-Van Dyke (BVD) equivalent electrical circuit com…


A Study on a Partially Immersed Gold Electrode Using an Electrochemical Quartz Crystal Impedance System
Qing Ji XIE, You Yu ZHANG, Ming SUN, Ling YI, Shou Zhuo YAO Chemical Research Institute,Hunan Normal University,Changsha .A Study on a Partially Immersed Gold Electrode Using an Electrochemical Quartz Crystal Impedance System[J].Chinese Chemical Letters,2000,11(9).
Authors:Qing Ji XIE  You Yu ZHANG  Ming SUN  Ling YI  Shou Zhuo YAO
Abstract:The electrochemical quartz crystal impedance system (EQCIS) has been used for the study of a partially immersed An electrode in 0.2 mol/L NaCIO_4. aqueous solution. The influences of the immersed area and height of the electrode on the EQCIS responses were evaluated, showing the highest response sensitivity to liquid loading at the center of the piezoelectric quartz crystal electrode. The increase in the immersed height of the An electrode at oxygen reduction potentials during potential cycling was measured by this technique.
Keywords:Electrochemical quartz crystal impedance system (EQCIS)  equivalent circuit parameters  electrochemical impedance  partially immersed An electrode  
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