Synthesis and structural peculiarities of gallium Complexes with novel paullone derivatives |
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Authors: | Werner Ginzinger Vladimir B. Arion Gerald Giester Markus Galanski Bernhard K. Keppler |
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Affiliation: | (1) Institute of Inorganic Chemistry, University of Vienna, A-1090 Vienna, Austria;(2) Institute of Mineralogy and Crystallography, University of Vienna, A-1090 Vienna, Austria |
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Abstract: | 9-Bromo-7,12-dihydroindolo[3,2-d][1]benzazepin-6-ylhydrazine was reacted with 2-acetylpyridine to give a Schiff base as a potential tridentate ligand. The reaction of this ligand with gallium chloride afforded complexes of 1:1 and 2:1 stoichiometry. The results of X-ray diffraction studies of the ligand and both gallium complexes are reported and compared with the data for a related gallium complex with a Schiff base obtained from 9-bromo-7,12-dihydroindolo[3,2-d][1]benzazepin-6-ylhydrazine and 2-hydroxybenzaldehyde. |
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Keywords: | Paullones Gallium complexes X-ray crystallography |
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