| Solvothermal Synthesis and Crystal Structure of a Novel Inorganic—Organic Hybrid Material,Fe2O（OH）（C5H4NCOO）SO4 |
| |
| 引用本文： | 郭洪猷,李增和,李秀艳,张长远,王如骥.Solvothermal Synthesis and Crystal Structure of a Novel Inorganic—Organic Hybrid Material,Fe2O（OH）（C5H4NCOO）SO4[J].中国化学,2003,21(4):466-470. |
| |
| 作者姓名： | 郭洪猷 李增和 李秀艳 张长远 王如骥 |
| |
| 作者单位： | Department of Chemistry，Beijing University of Chemical Technology，Department of Chemistry，Beijing University of Chemical Technology，Department of Chemistry，Beijing University of Chemical Technology，Department of Chemistry，Beijing University of Chemical Technology，Department of Chemistry，Tsinghua University Beijing 100029，China，Beijing 100029，China，Beijing 100029，China，Beijing 100029，China，Beijing 100083，China |
| |
| 摘 要： | IntroductionThereisatremendousactivityforthepastyearsintheareaofinorganic organichybridmaterialsinviewoftheirdi versifiedstructuresandinterestingproperties.1,2 Theeffortshavebeenmadeinsynthesizingandcharacterizingtheclassofmaterials.3Thecontrolofinorganicstructurebyanorganiccomponentrevealsaninteractivestructuralrelationinthema terials .4 Assemblyofaninorganic organichybridmaterialcanbeachievedbyselectingorganiccomponents (multidentateligands)andinorganiccomponents (transitionmetalions ,metalo…
|
| 关 键 词： | Fe2O（OH）（C5H4NCOO）SO4 有机－无机复合材料 合成 晶体结构 4－氰基吡啶 三氯化铁 |
Solvothermal Synthesis and Crystal Structure of a Novel Inorganic-Organic Hybrid Material, Fe_2O(OH)(C_5H_4NCOO)SO_4 |
| |
| Guo Hong‐You,Li Zeng‐He,Li Xiu‐Yan,Zhang Chang‐Yuan,Wang Ru‐Ji.Solvothermal Synthesis and Crystal Structure of a Novel Inorganic-Organic Hybrid Material, Fe_2O(OH)(C_5H_4NCOO)SO_4[J].Chinese Journal of Chemistry,2003,21(4):466-470. |
| |
| Authors: | Guo Hong‐You Li Zeng‐He Li Xiu‐Yan Zhang Chang‐Yuan Wang Ru‐Ji |
| |
| Abstract: | A novel inorganic‐organic hybrid material, Fe2O(OH)(C5H4‐NCOO)SO4 was synthesized via solvothermal route using a reaction of FeCl3 ·6H2O, KCNS, and 4‐cyanopyridne in aqueous solution of H2O2 and ethanol at 130 °C for 3 d. The compound crystallized in monoclinic space group P21, with cell parameters a=0.73850(15) nm, b = 0.65100(13) mn, c = 1.0546(2) nm, β = 90.36(3)°, V = 0.50700(18) nm3 and Z = 2. The structure is constructed with inorganic layered Fe2O(OH) SO4]+ cations linked by organic (C5H4NCOO)? anions. The compound is thermally stable up to approximately 240 °C. |
| |
| Keywords: | inorganic organic hybrid material ferric isonicotinate sulphate solvothermal synthesis crystal structure |
| 本文献已被 CNKI 等数据库收录！ |
