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Positive muons in [Co(NH3)6]Cl3 and [Co(ND3)6]Cl3
Authors:H. Kagetsu  N. Shioyasu  N. Fukunishi  M. K. Kubo  Y. Sakai  T. Tominaga  K. Nishiyama  K. Nagamine
Affiliation:(1) Department of Chemistry, University of Tokyo, Hongo, Bunkyo, 113 Tokyo, Japan;(2) Meson Science Laboratory, Faculty of Science, University of Tokyo, Hongo, Bunkyo, 113 Tokyo, Japan
Abstract:We have carried out mgrSR experiments on [Co(NH3)6]Cl3 and [Co(ND3)6]Cl3. At 293 K, all the muons implanted into the complexes were in the diamagnetic state. The observed Gaussian-type muon spin relaxation function proved that the internal magnetic field was caused by nuclear dipole moments of the atoms in the complexes. In addition, another exponential-type muon spin relaxation function was observed in [Co(ND3)6]Cl3 below 50 K.
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